There are some excellent texts which deal with particular areas of the chemistry of non-metal rings, cages and clusters in great depth but, with one or two exceptions, there are no useful introductions to this topic. In particular, upon entrapping an otherwise unstable metal cluster into a carbon cage, the so-called endohedral clusterfullerenes fulfil the mutual stabilization of the inner metal cluster and the outer fullerene cage with a specific isomeric structure which is often unstable as an empty fullerene. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. from the ACS website, either in whole or in part, in either machine-readable form or any other form Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. 50, 79 (1999). Find more information about Crossref citation counts. T. M. Bernhardt, Gas-phase kinetics and catalytic reactions of small silver and gold clusters, Int. In particular, the importance of the cluster size-effect and metal–support interactions in determining the catalytic performance of SMCs is highlighted. Information. These metrics are regularly updated to reflect usage leading up to the last few days. Metal cluster chemistry is at the cutting edge between molecular and solid-state chemistry and has therefore had a great impact on the researchers working on organic, coordination, and solid-state chemistry, catalysis, physics, and materials science. Beijing National Laboratory for Molecular Sciences, College of Chemistry and Molecular Engineering and College of Engineering, and BIC-ESAT, Peking University, Beijing 100871, China, Department of Chemistry and Guangdong Provincial Key Laboratory of Catalysis, Southern University of Science and Technology, Shenzhen, Guangdong 518055, China, State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan, Shanxi 030001, China, National Energy Center for Coal to Liquids, Synfuels China Technology Co., Ltd, Beijing 101400, China, Center for Integrative Materials Discovery, Department of Chemistry and Chemical Engineering, University of New Haven, West Haven, Connecticut 06516, United States, Supported Metal Clusters: Fabrication and Application in Heterogeneous Catalysis, Your Mendeley pairing has expired. In addition, based on computational modeling of SMCs, theoretical calculations corroborated well with experimental results, providing in-depth insights into the structure–property relationship for SMCs in catalysis. Mass Spectr. the Altmetric Attention Score and how the score is calculated. You’ve supercharged your research process with ACS and Mendeley! https://pubs.acs.org/doi/10.1021/acscatal.0c02818, http://pubs.acs.org/page/copyright/permissions.html. redistribute this material, requesters must process their own requests via the RightsLink permission Please reconnect. In this Review, classic synthetic strategies and key characterization techniques of SMCs are summarized. Different from isolated metal atoms and large metal nanoparticles (NPs), supported metal clusters (SMCs) possess distinct geometric and electronic structures and thus exhibit enhanced activity and designated selectivity in catalysis. Users are system. The American Chemical Society holds a copyright ownership interest in any copyrightable Supporting Electronic Supporting Information files are available without a subscription to ACS Web Editions. Detailed information on atomic numbers of supported metal species and corresponding average metal–metal coordination numbers is shown in Table S1 (PDF). Magnetic properties of alkali metal clusters in zeolite cages Rev. Lastly, challenges and prospects in SMCs’ catalysis are illustrated. Subsequently, the applications of SMCs in important catalytic reactions based on recent studies are discussed, including aerobic oxidation, hydrogenation, dehydrogenation, water–gas shift (WGS) reaction, and photocatalytic reactions. Therefore, the aim of this book is to form a comprehensive introduction to this very important area of inorganic chemistry. J. So far, with the development in synthetic methodologies and characterization techniques, SMCs with fine structures could be constructed and well-defined at the atomic level. Information about how to use the RightsLink permission system can be found at Molecular metal atom clusters or atomic species are comprised of at least two or more metal atoms attached to each other, notwithstanding being bonded to other nonmetals. http://pubs.acs.org/page/copyright/permissions.html. without permission from the American Chemical Society. Chem. You have to login with your ACS ID befor you can login with your Mendeley account. For permission to reproduce, republish and The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acscatal.0c02818. Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Metal cluster complexes exhibit many useful catalytic, optical, and other potentially useful properties for materials science applications, and many impressive advances have been made with respect to their synthesis. Get article recommendations from ACS based on references in your Mendeley library. M. B. Knickelbein, Reactions of Transition Metal Clusters with Small Molecules, Ann. Please note: If you switch to a different device, you may be asked to login again with only your ACS ID. 2 In a cluster atoms form a cage-like structure 3 There are a great number of known neutral and anionic hydroborane clusters 4 These structures are often described as being polyhedral or deltahedral 5 A deltahedron is a polyhedron that possesses only triangular faces, e.g., an octahedron 5.03 Lecture 6 Polyhedral Boranes and Wade’s Rules .
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